Product ID:PT 230 TRI-DIE, 19-0230
MSDS Date:05/03/1990
FSC:6850
NIIN:00N011288
MSDS Number: BHZBY

WHITMIRE RESEARCH LABORATORIES INC

3568 TREE COURT IND BLVD
ST LOUIS, MO 63122
US

Emergency Phone: 314-576-0120

Info Phone: 314-225-5371

Preparer: MICHAEL G SARLI

Cage: 67184

WHITMIRE MICRO GEN RESEARCH LABORATORIES, INC.

ST LOUIS, MO 63122-6620 US

Telephone: 636-225-5371

Cage: 67184

SILICA, AMORPHOUS, PRECIPITATED AND GEL

CAS: 7699-41-4

RTECS: VV8850000

Fraction By Weight: 4.0%

OSHA PEL 20 MPPCF

ACGIH TLV: 10 MG/M3 TDUST; 9293

TECHNICAL PIPERONYL BUTOXIDE

CAS: 51-03-6

RTECS: XS8050000

Fraction By Weight: 3.0%

OSHA PEL N/K

ACGIH TLV: N/K

ISOPARAFFINIC PETROLEUM SOLVENT

CAS: 64742-48-9

Fraction By Weight: 5.7%

OSHA PEL N/K

ACGIH TLV: N/K

PYRETHRUM (SARA III)

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 0.3%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHLORODIFLUOROMETHANE

CAS: 75-45-6

RTECS: PA6390000

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM; 9192

LD50 LC50 Mixture:LD50:(ORAL,RAT)>5000MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON & CHLOROFLUOROCARBON
(CFC) MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO
EPINEPHRINE IN LABORATORY ANIMALS AND COULD HAVE A SIMILAR EFFECT
IN HUMANS. ADRENOMIMETICS (I.E., EP INEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY
OR CHRONICALLY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EXPOSED TO CHLOROCARBONS & CFC'S .
ACUTE:EYE:PROD IS IRRITANT. SKIN:PRLNGD EXPOS MAY CAUSE IRRIT.
INGEST & INHAL:UNLIKELY DUE TO PROD BEING PRESSURIZED PROD &
PRODUCING PARTICLES LG ENO UGH NOT TO BE RESPIRABLE. FEW CASES OF
EXTRINSIC ASTHMA FROM PYRETHRIN MIX HAVE BEEN RPTD. PRLNGD EXPOS
MAY (SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES:FLUSH W/PLENTY OF WATER. SEEK MED ATTN. INGEST:CALL
PHYS/POIS CTL CTR IMMED. GASTRIC LAVAGE MAY BE INDICATED. DO NOT
INDUCE VOMIT. VOMIT MAY CAUSE ASPIR PNEUM. TREATMENT IS
SYMPTOMATIC. ANTIHISTA MINES ARE OF VALUE. INHAL:REMOVE VICTIMTO
FRESH AIR. APPLY ARTF RESP IF INDICATED. SKIN:REMOVE CONTAMD CLTHG
& WASH AFFECTED AREA W/SOAP & WATER. SEEK MED ATTN IF IRRIT
PERSISTS.

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:NONE REQUIRED. WEAR NIOSH/MSHA APPROVED
PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODUCTS MAY INCLUDE HCL,
FLUORIDES, CHLORIDES, AND PHOSGENE . CONTENTS UNDER PRESS. EXPOSURE
TO TEMPS ABOVE 130F MAY CAUSE BURSTING.

Spill Release Procedures:IF CNTNR BEGINS TO LEAK (THROUGH PUNCTURE,
ETC) ALLOW IT TO DISCHARGE COMPLETELY IN WELL VENTILATED AREA, THEN
DISPOSE IN SAFE PLACE. IN CASE OF SPILLAGE ON SKIN, WASH THORO WITH
SOAP & WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS UNDER PRESS. DO NOT PUNCTURE.
DO NOT STORE NEAR HEAT/OPEN FLAME. DO NOT REMAIN IN TREATED AREAS.
EXPOS TO TEMP ABOVE 130F MAY CAUSE (SUPDAT).
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR
PHOSGEN .

Respiratory Protection:NONE REQD IF APPLIED ACCORDING TO LABEL
DIRECTIONS. PROLONGED EXPOSURE OR WHEN EXPOSURE GUIDELINES
EXCEEDED, USE NIOSH/MSHA APPRVD PESTICIDE DUST RESPIRATOR.
Ventilation:MECHANICAL:PROVIDE ADEQ VENTILATION OF TREATMENT AREA.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED SAFETY GLASSES .
Other Protective Equipment:EYE WASH FOUNTAIN AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:FOODS/EATING UTENSILS SHOULD BE REMOVED/COVERED
DURING TREATMENT.
Supplemental Safety and Health
VAP PRESS IN AEROSOL CNTNR:3102. EFTS OF OVEREXP:CAUSE DRYING OF NOSE &
THROAT. MINIMAL ANESTH/NARC EFTS MAY BE SEEN IN RANGE OF 500-1000
PPM 1,1,1 TRICHLOROETHANE. WHEN USED ACCDG TO LBL DIRECTIONS L EV
WILL NOT BE ATTAINED. HNDLG/STOR PREC:BURSTING. AVOID SKIN CONT.
REMOVE PETS, BIRDS, & COVER FISH BOWLS (ING 8)

Vapor Pres:SUPDAT
Spec Gravity:0.90 (H*20=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SPRAYS AS TAN POWDER WITH A CHARACTERISITC
PYRETHRUM ODOR.
Percent Volatiles by Volume:87

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DO NOT SPRAY INTO OPEN FLAME OR ONTO VERY
HOT SURFACES.
Hazardous Decomposition Products:HCL, CHLORIDES, FLUORIDES AND PHOSGENE
. THERMAL DECOMP IN OPEN FLAME MAY RESULT IN HALOGEN ACIDS & CO*2.

Waste Disposal Methods:AEROSOL CYL IS NOT REFILLABLE. DO NOT ATTEMPT TO
RECHARGE. WHEN CYL IS EXHAUSTED, DISCARD IN SAFE PLACE. DO NOT
THROW INTO FIRE. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATION S .

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.